Combining in situ isotopic, trace element and textural analyses of quartz from four magmatic-hydrothermal ore deposits   总被引：2，自引：0，他引：2  

Dominique Tanner  Richard W. Henley  John A. Mavrogenes  Peter Holden 《Contributions to Mineralogy and Petrology》2013,166(4):1119-1142

This study couples in situ ¹⁶O, ¹⁷O and ¹⁸O isotope and in situ trace element analyses to investigate and characterize the geochemical and textural complexity of magmatic-hydrothermal quartz crystals. Euhedral quartz crystals contemporaneous with mineralization were obtained from four magmatic-hydrothermal ore deposits: El Indio Au–Ag–Cu deposit; Summitville Au–Ag–Cu deposit; North Parkes Cu–Au deposit and Kingsgate quartz-Mo–Bi–W deposit. The internal features of the crystals were imaged using cathodoluminescence and qualitative electron microprobe maps. Quantitative isotopic data were collected in situ using 157 nm laser ablation inductively coupled plasma mass spectrometry (for 40 trace elements in quartz) and sensitive high-resolution ion microprobe (for 3 isotopes in quartz). Imaging revealed fine oscillatory zoning, sector zoning, complex “macromosaic” textures and hidden xenocrystic cores. In situ oxygen isotope analyses revealed a δ¹⁸O range of up to 12.4 ± 0.3 ‰ in a single crystal—the largest isotopic range ever ascribed to oscillatory zonation in quartz. Some of these crystals contain a heavier δ¹⁸O signature than expected by existing models. While sector-zoned crystals exhibited strong trace element variations between faces, no evidence for anisotropic isotope fractionation was found. We found: (1) isotopic heterogeneity in hydrothermal quartz crystals is common and precludes provenance analysis (e.g., δD–δ¹⁸O) using bulk analytical techniques, (2) the trace element signature of quartz is not an effective pathfinder toward noble metal mineralization and (3) in three of the four samples, both textural and isotopic data indicate non-equilibrium deposition of quartz.  相似文献   

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108     

Wafa Abouchami  Stephen J. G. Galer  Tristan J. Horner  Mark Rehkämper  Frank Wombacher  Zichen Xue  Myriam Lambelet  Melanie Gault‐Ringold  Claudine H. Stirling  Maria Schönbächler  Alyssa E. Shiel  Dominique Weis  Philip F. Holdship 《Geostandards and Geoanalytical Research》2013,37(1):5-17

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.  相似文献   

Comment on Duplex at the lateral tip of a thrust fault: the “La Cagalière” example (NE Pyrenees,France) by C. Souque et al     

Bernard Laumonier  Christian Marignac  Dominique Gasquet 《Geodinamica Acta》2013,26(2):179-181

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Seasonal changes in zooplanktonic alkaline phosphatase activity in Toulon Bay (France): the role of Cypris larvae     

Jean N  Bogé G  Jamet JL  Richard S  Jamet D 《Marine pollution bulletin》2003,46(3):346-352

We studied zooplankton contribution to the total particulate phosphatase activity, the kinetics of this activity, the relation to the different taxonomic groups and the role of particle-bound bacteria. The activity of total particulate material collected from a liter of seawater was more elevated in May, June and August than during the rest of the year. These high activities resulted from a high contribution of the >90 microm fraction which account then for more than 60% of the total particulate activity. Two Michaelian processes with high and low V(max) were disclosed on this fraction. The high V(max) component was responsible for the high summer activities. During these periods, high densities of cirriped Cypris were found which were statistically correlated with this high V(max) component as with its specific activity. Moreover, the contribution of attached bacteria to these high activities was low. In return, this contribution was predominant during the periods of low activity. A simple method was developed to characterise this bacterial activity.  相似文献   

Asymptotic regimes in unstable miscible displacements in random porous media     

Z.M. Yang  Y.C. Yortsos  Dominique Salin 《Advances in water resources》2002,25(8-12)

We study two asymptotic regimes of unstable miscible displacements in porous media, in the two limits, where a permeability-modified aspect ratio, R_L=L/H(k_v/k_h)^1/2, becomes large or small, respectively. The first limit is known as transverse (or vertical) equilibrium, the second leads to the problem of non-communicating layers (the Dykstra–Parsons problem). In either case, the problem reduces to the solution of a single integro-differential equation. Although at opposite limits of the parameter R_L, the two regimes coincide in the case of equal viscosities, M=1. By comparison with high-resolution simulation we investigate the validity of these two approximations. The evolution of transverse averages, particularly under viscous fingering conditions, depends on R_L. We investigate the development of a model to describe viscous fingering in weakly heterogeneous porous media under transverse equilibrium conditions, and compare with the various existing empirical models (such as the Koval, Todd–Longstaff and Fayers models).  相似文献   

The Projects for Onboard Autonomy (PROBA2) Science Centre: Sun Watcher Using APS Detectors and Image Processing (SWAP) and Large-Yield Radiometer (LYRA) Science Operations and Data Products     

J. Zender  D. Berghmans  D. S. Bloomfield  C. Cabanas Parada  I. Dammasch  A. De Groof  E. D’Huys  M. Dominique  P. Gallagher  B. Giordanengo  P. A. Higgins  J.-F. Hochedez  M. S. Yalim  B. Nicula  E. Pylyser  L. Sanchez-Duarte  G. Schwehm  D. B. Seaton  A. Stanger  K. Stegen  S. Willems 《Solar physics》2013,286(1):93-110

The PROBA2 Science Centre (P2SC) is a small-scale science operations centre supporting the Sun observation instruments onboard PROBA2: the EUV imager Sun Watcher using APS detectors and image Processing (SWAP) and Large-Yield Radiometer (LYRA). PROBA2 is one of ESA’s small, low-cost Projects for Onboard Autonomy (PROBA) and part of ESA’s In-Orbit Technology Demonstration Programme. The P2SC is hosted at the Royal Observatory of Belgium, co-located with both Principal Investigator teams. The P2SC tasks cover science planning, instrument commanding, instrument monitoring, data processing, support of outreach activities, and distribution of science data products. PROBA missions aim for a high degree of autonomy at mission and system level, including the science operations centre. The autonomy and flexibility of the P2SC is reached by a set of web-based interfaces allowing the operators as well as the instrument teams to monitor quasi-continuously the status of the operations, allowing a quick reaction to solar events. In addition, several new concepts are implemented at instrument, spacecraft, and ground-segment levels allowing a high degree of flexibility in the operations of the instruments. This article explains the key concepts of the P2SC, emphasising the automation and the flexibility achieved in the commanding as well as the data-processing chain.  相似文献   

Eclipses Observed by Large Yield RAdiometer (LYRA) – A Sensitive Tool to Test Models for the Solar Irradiance     

A. I. Shapiro  W. Schmutz  M. Dominique  A. V. Shapiro 《Solar physics》2013,286(1):271-287

We analyze the light curves of the recent solar eclipses measured by the Herzberg channel (200?–?220 nm) of the Large Yield RAdiometer (LYRA) onboard Project for OnBoard Autonomy (PROBA2). The measurements allow us to accurately retrieve the center-to-limb variations (CLV) of the solar brightness. The formation height of the radiation depends on the observing angle, so the examination of the CLV provide information about a broad range of heights in the solar atmosphere. We employ the 1D NLTE radiative transfer COde for Solar Irradiance (COSI) to model the measured light curves and corresponding CLV dependencies. The modeling is used to test and constrain the existing 1D models of the solar atmosphere, e.g. the temperature structure of the photosphere and the treatment of the pseudo-continuum opacities in the Herzberg continuum range. We show that COSI can accurately reproduce not only the irradiance from the entire solar disk, but also the measured CLV. Hence it can be used as a reliable tool for modeling the variability of the spectral solar irradiance.  相似文献   

Surveying flash floods: gauging the ungauged extremes   总被引：1，自引：0，他引：1  

Marco Borga  Eric Gaume  Jean Dominique Creutin  Lorenzo Marchi 《水文研究》2008,22(18):3883-3885

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C^k-Reconstruction of Surfaces from Partial Data     

Dominique Apprato  Christian Gout  Pascale Sénéchal 《Mathematical Geology》2000,32(8):969-983

In this paper, we study the problem of constructing a smooth approximant of a surface defined by the equation z = f(x ₁, x ₂), the data being a finite set of patches on this surface. This problem occurs, for example, after geophysical processing such as migration of time-maps or depth-maps. The usual algorithms to solve this problem are picking points on the patches to get Lagrange's data or trying to get local junctions on patches. But the first method does not use the continuous aspect of the data and the second one does not perform well to get a global regular approximant (C ¹ or more). As an approximant of f, a discrete smoothing spline belonging to a suitable piecewise polynomial space is proposed. The originality of the method consists in the fidelity criterion used to fit the data, which takes into account their particular aspect (surface's patches): the idea is to define a function that minimizes the volume located between the data patches and the function, and which is globally C ^k. We first demonstrate the new method on a theoretical aspect and numerical results on real data are given.  相似文献   

Analysis of Transient Data from Infiltrometer Tests in Fine-Grained Soils     

Dominique Guyonnet  Nadia Amraoui  Reda Kara 《Ground water》2000,38(3):396-402

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